We further found the carbenium ion stability to be a quantitative reactant-type descriptor, correlating with the C–H activation barriers of the different alkanes. UOP Oleflex User Conference, USA, 2001. In general, Rh−Al2O3 catalyst was found to be excellent in activity and selectivity. The lowest yield of isobutene was in the case of 1-butanol. Nawaz Z, Wei F. Hydrothermal study of Pt-Sn-based SAPO-34 supported novel catalyst used for selective propane dehydrogenation to propylene. Zhao H, Song H, Xu L, Chou L. Isobutane dehydrogenation over the mesoporous Cr2O3/Al2O3 catalysts synthesized from a metal-organic framework MIL-101. Prom-st. 31, 10 (1933). Jibril BY, Al-Zahrani SM, Abasaeed AE, Hughes R. Oxidative dehydrogenation of propane over supported chromium-molybdenum oxides catalysts. A manganese phosphate catalyst was prepared, characterized (BET, FTIR and XPS), and tested for the reaction at atmospheric pressure and a temperature range of 450−550 °C. 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Weinheim: Wiley-VCH, 2009. to access the full features of the site or access our. However, because prior studies in flow reactors showed difficulty in self-coupling ethanol and 1-butanol over npAu in flow reactors, the inherent capability on npAu for self-coupling of ethanol and 1-butanol was examined under ultrahigh vacuum conditions on identical npAu catalysts. Faro AC, Souza KR, Camorim VLD, Cardoso MB. E-mail: Sattler JJHB, Martinez JR, Jimenez ES, Weckhuysen BM. UOP Oleflex process for light olefin production, 2013. Rather than belaboring underlying proofs and mathematical derivations, it emphasizes optimization methodology, focusing on techniques and stratagems relevant to engineering applications in design, operations, and analysis. catalyst for isobutane dehydrogenation. Make C3–C4 olefins selectively. A satisfactory description of the reaction rate depended on inclusion of the isobutene and hydrogen adsorption parameters in the mathematical model. 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The possible solution for improvement is by focusing on catalyst improvements and the unique design of reactors. of the whole article in a thesis or dissertation. Chin Patent Appl 200910091226.6, 2009. J R Inst Thai 2002, 27: 664–672. Nawaz Z, Wei F. Integrated bi-modal fluidized bed reactor for butane dehydrogenation to corresponding butylenes. We revealed that doping (100) γ-Al2O3 with Ga atoms has significant improvement in the dehydrogenation activity by decreasing the C–H activation barriers of the kinetically favored concerted mechanism and increasing the overall dehydrogenation turnover frequencies. Catal Lett 2007; 119: 283–288. Nawaz Z, Tang XP, Wang Y, Wei F. Parametric characterization and influence of tin on the performance of Pt-Sn/SAPO-34 catalyst for selective propane dehydrogenation to propylene. Appl Catal A 2003; 254: 261–272. This study shows that the oxygen-covered Ag-modified npAu does efficiently effect the self-coupling of ethanol and 1-butanol under UHV conditions. Paper AM-94-28, Annual Meeting of the National Petroleum Refiners, 1994. Join ResearchGate to find the people and research you need to help your work.
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